I use Rustoleum 2 in 1 filler and sandable primer. It works great on 3D printed items. I wet sand after 2 or 3 coats. I prime again after that as needed.
I use 220 up to 400 grit wet sandpaper to smooth out layer lines and imperfections.
You're also going to want to pick up a set of needle files. They can save the day for smoothing layer lines out of tight corners where the sand paper can't get into.
For silver, particularly aluminum, I use Rustoleum Imagine silver. In 1 or 2 coats you have a very convincing metal surface. I have only ever found it at Target. I order it from their website now as I live far away from a Target store. But they have always had it in stock.
Once it's cured it can be handled without any dulling.