I like to use silicone as a mold rubber.It may cost a tad more, but it alleivaites allot of potential problems.Of course,there are pros and cons to using everyting and you do have to be careful/knowledgable about certain products that may not work with RTV silicone.Some have negative,reactive properties.Sulfur is a big one as are some resins and other products.I also prefer to use urethane resin for castings.The shrinkages is negligable as opposed to polyester.Again,there's always a trade off.Urethane costs a bit more and often times you have a limited potlife.Some set in 2-3 min others may have a slow setting time and take 10 min.Urethanes tend to attack mold rubbers too.Its a mixed bag and I suppose much depends on what you are wanting to accomplish?