My $0.02:
Fiberglass is the most durable materal for a trooping bucket. Both resin and 3D print will look nice, but one drop to the concrete (and we've ALL done it!) and it could crack or shatter like glass!
With that said, NOT ALL FIBERGLASS IS EQUAL. Remember, this is going to cover your head!
Polyester resin has a very nasty odor and it is cheaper, most builders use it.
Epoxy resin has no smell, and is better for buckets. It is costlier, and not as easy as polyester resin to use. Fewer artists use this
Fiberglass comes in MAT and CLOTH, Depending on who laminated your helmet, you can have fiberglass SPLINTERS that are very sharp and dangerous. Use caution before placing on head! If the lamination is finished with cloth, you have a smoother surface on the inside where your head is.
SUMMARY: The best Fiberglass option is a bucket with Epoxy and 2 layers of cloth. Second choice would be the Polyester and Mat (Be sure to sand the inside and seal with paint.
As far as resin helmets, I wear them, but if you drop one, it is going to break. Also, one additional Caveat: Because this is a Mandalorian, it is open on the bottom with nothing to stiffen the shape, The helmet can warp out of shape and collapse if left in a hot car.
3D Printed: This will be a beautiful helmet, but needs a lot of surface work to hide the print texture. Also keep in mind that it will satter if dropped.