What you could do is find an action figure .pdo or .obj that matches your posture/shoulder width,but slightly more bulky,and duplicate this in EVA foam.This way the torso is strong enough to carry a collar (e.g.Iron Man Classic collar,see JfCustom's foam files page1).Scale this slightly smaller than the dome (approx. 10") and to match the top of your EVA foam torso.You could use magnets to firmly hold the collar in place to prevent wobbling of the dome and collar,as well as where the collar meets the edge of the dome to keep the dome in place.
You could then use shoulder pads of lets say the Saiyan armor .pdo to slightly 'lift' your shoulders (if the muscle suit didn't do this already).The cape can then rest unto these pads with magnets or velcro on top of them to hold the cape in place,ofcourse mindful of how much the pads would stick out sideways.This prevents you from looking 'wrapped in your cape' rather than you wearing one.If this causes to much of a pull backwards,you could then put magnets inside the 'eyes' that rest on Mysterio's chest and have them hold the cape in place.
I hope that helps.Oh,and don't forget the fan or fans inside the helmet with an opening (e.g.through the collar).Looking forward to seeing this develop!