A couple of thoughts, depending on the silicone, tin or platinum, something from the resin might be reacting, causing it to stick. If I remember correctly, the tin based will stick to glass as well. You might want to spray a clear coat to seal it then give it a try.
Another problem I had before, some uncured silicone was on the part, when I then put in in a silicon mold, the resin stuck. I had to destroy the mold getting the part out. If this is the case, try cleaning the part (scrub with alcohol.)