No mold release is needed for silicone rubber. If you are asking about a release when making a multiple part mold, so rubber doesn't stick to rubber, vaseline is the stuff. Use a wide, flat brush to apply the vaseline so it is just a film, no streaks. Do this just before you pour the rubber or the vaseline will dry out.
The reason using a mold release is useless is that nothing sticks to silicone rubber. You can put a layer of spray paint in a mold and then pour the material and you'll see the paint pulls loose by how the paint appears on the casting.
Scott