Sounds pretty unfeasible. Plaster is hard and brittle and not great to work with, you would definitely need something to support it. You could maybe try to build up plaster over a wire mesh form or something but it'd be unnecessarily hard, constantly cracking etc.
You could have a go at sculpting in clay, it's nice and pliable and it doesn't matter if you mess up just throw some more on and re-sculpt.
My preferred method would be to make the basic shape out of card and then smooth it over with bondo (or plaster if you prefer). (if you're not comfortable sculpting then someone may have already made a pepakura model you can use)
Whilst it can be hard trying a new technique, both of these require only a small investment and will be a lot easier than trying to build it entirely from plaster.