If you want your mold to make casts with a glossy finish, you have to clean the mold release off the master before pouring the silicone, or use a glossy self-leveling mold-release as stated above.
Any mold release you spray inside the mold for casting is going to impact the surface finish of casts a little. If you're painting or clear-coating the casts, just use Mann Ease-Release 200 and sand them before painting. If you need them perfectly gloss-clear right out of the mold, just cast them without spraying the mold with release.