Here's what Pilot PM'd me..for all to share...Thanks my friend
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If your version of PDVD is close to mine (and I have a fairly new one,) The setup should be as follows:
-Open the program *without* a DVD in the drive, then right-click on what would normally be the playback screen and select "Configuration."
-From the "General" tab, select the "Advanced" button.
-Select the "Capture" tab.
-Tick off the "Capture to File" radio button, and plug in the save path you want your image files to end up in.
-That's about it...keep mashing that "C" key during playback, and reap the rewards of your efforts.
If the menu options you have don't jive 100% with mine, just poke around a little bit. They should all be in the same general area.
Hope that helps. If you still have issues, I'll be glad to help you out further.