When using a 10:1 or 20:1 type silicone rtv, I tend to error on the side of too much catalyst. My understanding is that a little too much catalyst won't hurt it, but not enough could possibly keep it from curing thoroughly.
Or you could always go with a 1:1 (by volume) type rtv. They are very easy to use, but the mold is not as durable.
Smooth-On is a very popular source for rtv. My favorite was a sample I got years ago for free from GE Silicone. Unfortunately it is not available any more.
-Marx