Thank you all so much for all the info!
cavx, I thought the problem with using epoxy in molds was that the material never fully cured? The last time I heard of someone using epoxy, when the opened the mold, the surface stayed sticky. Or is the epoxy you are talking about something specifically for molding?
Sometimes Polyester resins remain sticky on the surface, but I have never had that issue with epoxy. If the epoxy is not curing properly, then I will suggest it was not mixed properly and some people think they can mix this gently to reduce bubbles. No, you must mix this stuff up hard and fast and then degassing is the best way to have a bubble free pour. Pressure pot finishes it off if you have one.
The stuff I use is same epoxy that was sold as a 3D print smoother. They self level and fill in an small lines giving a glassy smooth finish without the need to sand. When you cast this stuff, you must be aware that it gets super hot and this can burn the molds! Then again, so can polyester resin if too much cat is added.
There are two different versions of epoxy now in Australia - original would yellow over time and was mixed at 100:50, but it cheap and good for making all sorts of stuff that you need a hard plastic for. It can be tinted and holds the true colour. The new stuff is UV stable and mixed at 100:100, costs a fair bit more (almost double), but much nicer product and stays water clear.
On the original pack, the instructions said 3 hour cure time, however you could have issues if demolding under 6 hours. I had a part that looked like it was made some form of expanding foam when I demolded too early as it swelled up. I found 6 hours to be really good for the parts I was making.
However, there is then a post cure time of 48 hours where the part can deform if stressed until it fully hardens. I found this useful because even though the part was cured, it was still flexible and could be shaped in a jig and left to set hard. After the 48 hours, it is hard plastic. One thing I like about epoxy is that I have dropped cast parts on concrete and they just bounce. Same parts made from Polyurethane parts tend to crack.