Chicago Latex Products carries a material called "neoprene". It works the same way as mask latex does, in that you pour it into a plaster/stone mold and let it dwell for a period of time to get the desired thickness. You than pour the material out, and what remains is your mask (just like mask latex). The difference is, that unlike liquid latex, neoprene continues to harden once the piece is de-molded. They offer flexible, semi-rigid, and rigid. The rigid material once dried completely has the feel of a thin fiberglass piece (meaning that you can still flex it slightly - but really holds it shape without back filling with another material). My kids used it on some ALIEN heads a number of years ago, and it worked out great. Held the shape despite the long profile of that character. The material can be drilled, sanded etc.
Best of luck,
BHSFX
www.bhsfx.org