I wonder what would happen if you had a rotocast that could fit into a pressure pot.
Also since it dosen't have to be clear, just frosted, you could always pour your mold open to get a thin layer like a rotocast, then join the two halves together with more resin along the seam, maybe add some cabisil to make it pasty.
don't know if you would need to vacum degass it, could help though.