Scroll down to the second product on the page, "Honey Wax" in the yellow tin.
I've never had a casting failure with it, you can polish your mould up to the point that it almost looks like glass and depending on the shape of your mould, you can get your casts to just fall out! Obviously the more complex the shape, the more the demoulding time will take.
I've used lots of other products, but having found this stuff, I've never looked back.
I haven't had a problem with PVA--it just takes a good HVLP gun to spray a few good clean smooth layers of it for the best results. I love that it's a water cleanup.
A few good coats of plain old Carnauba car wax works too, as said any undercuts and you are in trouble...
PVA works as well but if pulled surface is important it can cause issues if the PVA pools in the mold, or leaves other surface imperfections when being applied... PVA can't be beat as a back coating to the layup though if you are having 'sticky' or curing issues due to humidity and temp...
Cheers for the tips thus far.
To respond;
There is no gelcoat, just fibreglass, but that could change.
The shape has no undercuts, and has been designed to pull easily, like a pyramid with the top cut off.
Ta.