Oh my, I'm pretty late to the party but better late than never.
160gsm paper is my weapon of choice. It goes through the printer without issues and is thicker than regular office paper. Such a big sculpture will need a lot of reinforcement, especially at the ankles. To do so you can use any scrap paper and card you can get your hands on. Recycle cereal boxes, amazon packaging etc. But make sure that the material you use does not smell. Unfortunately most Pepakura models do not provide parts for an internal support structure, so you'll have to come up with a unique solution. I would assemble strategic sections of the model and glue additional layers of 160gsm paper or card to the inside to strengthen it (similar to how you work with paper maché). That however will increase the weight of the final piece so it is necessary to add a support inside the legs and feet. I don't know if you could fill any holes with expanding foam, you should test that as well (but be careful because of moisture effects and the rate of expansion).