Was it a 2 part mold or a 1 piece block mold? Sometimes with a small part in a one piece mold you need to break the surface tension to get the cast part to release. What are you molding? Are there any serious undercuts?
You might want to spray it will one of Smooth-On's release agents before you mold it in the silicone. It will help relieve the surface tension as well.
Randy