Some of the flexible costumes (masks, etc.) are more lenient on materials in listing Latex, Silicone, rubber, etc. Most all armored costumes are ABS, Fiberglass, PVC. 501st is more structured in the requirements that some groups, but even the Mandalorian Mercs which allow a lot of flexibility in creating your armor have not allowed EVA.
If you want, check out youtube videos on building clonetrooper armor from plasticard and lining it with foam. Because the main structure is plastic, the exterior "could" look rather convincing.
Each 501st costume goes through an approval process as well in sending to the area's garrison membership liaison and they will tell you changes needed, etc.
As a 501st member myself and many...many costumes registered I can tell you the effort is worth it if you put time into it.
My costumes:
Approved:Imperial Staff Officer, Snowtrooper, Imperial Gunner, Reserve Pilot, ANH Tie, ROTJ Tie, 181st Tie, Baron Fel, Bridge Crew, Sandtrooper
In Progress: 181st Dress Uniform 100% done, Warrant Officer 100% done, TFA Tie Pilot 60%, Hondo Ohnaka 25%, Clone Trooper 10%, Bossk 10%