So, Spider-Man 1 Suit it is. After exporting my file to jpeg, it almost looks a bit orange as a thumbnail, but I'm pretty positive it will print good since I used the same red color for another suit I had made.
Found this really nice reference pic of the 2002 suit.
I'm actually going to attempt sculpting my own eye frames, make a mold and then cast in urethane rubber. The SM1 suit really has whiter eyes than the 2004-2007 version, so that's something I want to achieve.
I only have red puffpaint atm, but I did a test on a piece of scrap lycra to get an idea of the thickness. I want the puffpaint to be really thick and pop out. Decided on using silver puffpaint despite not being perfectly accurate to the movie suit. Metallic Black looks too dark in my opinion.
Webbing test piece:
Note: I rushed the test piece, the webs on the suit will be alot smoother.