The easiest way to do a lifecast (the technical term for a facial cast) is with those plaster bandages you get at any hobby/craft store. You'll have to grease your face up with vaseline to prevent sticking, and extra so on facial hair (eyebrows, etc.). This is the simplest and cheapest method of lifecast, but the least detailed. However, if you just want to shape a mask to your face, you merely need the shape, not the details of your pores, etc that pick up in the more detailed casting agents such as alginate or silicone.
Alginate backed by plaster bandages is the next step up, then there's silicone backed by plaster bandages. These both capture detail incredibly and are pretty much only necessary if you want to make a severed limb that has skin texture. You have to be careful with the silicone though as only certain types (like smooth-on's Body Double) are formulated to go directly on skin without poisoning you. The difference between alginate and silicone (for practical purposes) is that silicone is archival and alginate is not. That is to say that alginate dries up and shrinks over a short period of time and becomes non-usable, while silicone remains indefinitely.
In short. Go get some plaster bandages from Michael's and a tub of vaseline and call it a day. No need to monkey around with alginate or silicone.