Morning, it would depend on a few things. I used Hot Wire Foam Factory hard coat products in my theater. But that leave a very rough stone like texture, and if you're handling the prop, it probably wouldn't hold up. The other product I almost used, was Styrospray 1000. It's a thin layer of plastic that coats the prop and it appears very robust. It's a bit in the pricy side though, so a large prop may be expensive. It can be painted on or sprayed on if I'm not mistaken? There are some reviews of it on the forum.
What are you making exactly?
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You can also fiberglass over it if you properly prepare the foam, otherwise it would definitely melt it.