Yeah its a familiarity thing. I started with no 3d modeling experience and Sketchup is the easiest to bash out simple things.
I use Blender to do model smoothing and shell commands but nothing else. (Its scary to use lol) Or i get a friend to use Max/Maya.
Netfabb free does great slicing and basic repairs (although on complicated models it causes more problems that it fixes sometimes) and i believe the pro version does shell (Cant confirm first hand).
I generally only sand my 3d printed parts as acetone vapour rounds off all the sharp edges. I havent tried painting it on yet, but i have been thinking about using acetone and sandpaper to quickly take the print grain off (Untested). Currently I've been wearing the prints as they are one offs (and are under IP) but down the line ill be casting, and may even do throw away casts so they can be sanded/finished quickly.
The printer i use is the UP plus 2 which has a perf board (print bed with holes) and is rock solid for holding prints down.
Have you got any links to your 3d stuff? I'd be keen to check it out